WebFeb 1, 2024 · The reaction mechanism of PPAT involves a nucleophilic attack by 4′-phosphate of phosphopantetheine on the α-phosphate of ATP in an in-line displacement mechanism, where both the substrates are positioned in a single line. This results in a short lived intermediate pentacovalent transition state. WebStructural and binding studies of phosphopantetheine adenylyl transferase from Acinetobacter baumannii. Phosphopantetheine adenylyltransferase (PPAT, EC. 2.7.7.3) …
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WebUsing Escherichia coli LipB as a model enzyme, we show here that the octanoyl-transferase mainly recognizes the 4'-phosphopantetheine-tethered acyl-chain of its donor substrate and weakly binds the apo-acyl carrier protein. We demonstrate LipB can accept octanoate from its own ACP and noncognate ACPs, as well as C8-CoA. Web4'-Phosphopantetheine C11H23N2O7PS CID 115254 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, … how is inspector goole presented in act 1
CDD Conserved Protein Domain Family: PP-binding - National …
WebJul 17, 2024 · A phosphopantetheine-binding-induced activation mechanism To verify our hypothesis, we determined the crystal structure of the CAR sr PCP–reductase (PCP–R) … WebOct 5, 2007 · Together with docking simulations that identified a potential phosphopantetheine binding groove, the structural and functional studies reveal that the C9 specificity is a result of active site geometry and substrate ring constraints. The results lay the foundation for the design of novel aromatic polyketide natural products with different ... WebApr 16, 2014 · Protein has 1 cofactor binding site: pantetheine 4'-phosphate ( UniProtKB Rhea CHEBI:47942 ) By similarity Note: Binds 2 phosphopantetheines covalently. By similarity Pathway Siderophore biosynthesis; mycobactin biosynthesis. GO annotations Expand table Complete GO annotation on QuickGO Keywords Molecular function # Ligase highland park ford illinois